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化合物简介
Djenkolic acid (or sometimes jengkolic acid) is a sulfur-containing non-protein amino acid naturally found in djenkol beans of the South-East Asian legumes jengkol (Archidendron jiringa). This compound consists of two cysteine radicals connected by a methylene group between the sulfurs, or it is 2-amino-3-[(2-amino-3-hydroxy-3-oxopropyl)sulfanylmethylsulfanyl] propanoic acid. It is toxic to humans, especially causing nephrotoxicity.
基本信息
CAS:498-59-9
中文别名:3,3\'-(亚甲二硫)双丙胺酸;3,3\'-(亞甲二硫)雙丙胺酸;S-亚甲胱氨酸;
英文别名:S,S\'-Methylenedi-L-cysteine;L-Cysteine, S,S‘-methylenebis-;Djenkolic Acid;(2R)-2-amino-3-[[(2R)-2-amino-2-carboxyethyl]sulfanylmethylsulfanyl]propanoic acid;
分子式:C7H14N2O4S2
分子量:254.327
精确质量:254.039
Psa:177.24
Logp:0.6347
中文别名:3,3\'-(亚甲二硫)双丙胺酸;3,3\'-(亞甲二硫)雙丙胺酸;S-亚甲胱氨酸;
英文别名:S,S\'-Methylenedi-L-cysteine;L-Cysteine, S,S‘-methylenebis-;Djenkolic Acid;(2R)-2-amino-3-[[(2R)-2-amino-2-carboxyethyl]sulfanylmethylsulfanyl]propanoic acid;
分子式:C7H14N2O4S2
分子量:254.327
精确质量:254.039
Psa:177.24
Logp:0.6347
编号系统
UNII:3QHC9R0YFZ
物化性质
密度:1.501g/cm3
沸点:515.4ºC at 760 mmHg
闪点:265.5ºC
折射率:-65 ° (C=1, 1mol/L HCl)
蒸汽压:5.2E-12mmHg at 25°C
沸点:515.4ºC at 760 mmHg
闪点:265.5ºC
折射率:-65 ° (C=1, 1mol/L HCl)
蒸汽压:5.2E-12mmHg at 25°C
安全信息
安全说明:S24/25
WGK Germany:3
危险类别码:R10
海关编码:2930909090
危险品运输编码:1993
WGK Germany:3
危险类别码:R10
海关编码:2930909090
危险品运输编码:1993
生产方法及用途
合成路线
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参考文献
Armstrong; du Vigneaud Journal of Biological Chemistry, 1947 , vol. 168, p. 374
上游原料
下游产品
图谱
13C NMR : Predict
1H NMR : Predict
Mass
IR : KBr disc







