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化合物简介

The terpinenes are a group of isomeric hydrocarbons that are classified as terpenes. They each have the same molecular formula and carbon framework, but they differ in the position of carbon-carbon double bonds. α-Terpinene has been isolated from cardamom and marjoram oils, and from other natural sources. β-Terpinene has no known natural source, but has been prepared synthetically from sabinene. γ-Terpinene and δ-terpinene (also known as terpinolene) are natural and have been isolated from a variety of plant sources.

基本信息

CAS:99-85-4
中文别名:γ-萜品烯,松油烯;1-甲基-4-(1-异丙基)-1,4-环己二烯;1-甲基-4-(1-甲基乙基)-1,4-环己二烯;γ-萜品烯;
英文别名:1-methyl-4-propan-2-ylcyclohexa-1,4-diene;gamma-terpinene;1,4-Cyclohexadiene, 1-methyl-4-(1-methylethyl)-;p-Mentha-1,4-Diene;
分子式:C10H16
分子量:136.234
精确质量:136.125
Psa:0.0
Logp:3.3089

编号系统

UNII:4YGF4PQP49

物化性质

外观与性状:无色至淡黄色液体
密度:0.85g/mLat 25°C(lit.)
沸点:182°C(lit.)
熔点:60-61ºC
闪点:125°F
折射率:n20/D 1.474(lit.)
储存条件:2-8ºC
蒸汽密度:4.7 (vs air)
蒸汽压:~0.7 mm Hg ( 20 °C)

安全信息

RTECS号:OS8070000
安全说明:S26; S36
WGK Germany:2
危险类别码:R10; R36/37/38
海关编码:2902199090
危险品运输编码:UN 2319 3/PG 3
危险类别:3.2
包装等级:III
危险品标志:Xi
信号词:Warning
危险标志:GHS02, GHS07
危险性描述:H226; H315; H319; H335
危险性防范说明:P261; P305 + P351 + P338

生产方法及用途

生产方法
由马缨丹(Lantana camara)精油分离而得。 由对异丙基甲苯在液氨中用乙醇和钠反应(Birch反应)而得。 本品广泛用于调配香精及复配精油。
用途
本品广泛用于调配香精及复配精油。

合成路线

上游原料

下游产品

图谱

Predict 1H proton NMR


13C NMR : Predict


1H NMR : Predict


13C NMR : in CDCl3


1H NMR : 90 MHz in CDCl3


Mass


IR : liquid film


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