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化合物简介
                2,4,6-Trihydroxyacetophenone (THAP) is a phloroglucinol.
            
            基本信息
                CAS:480-66-0
中文别名:2\',4\',6\'-三羟基乙酰苯一水合物;2,4,6-三羟基苯乙酮;2\',4\',6\'-三羟基苯乙酮一水合物;
英文别名:2,4,6-Trihydroxyacetophenone;2‘,4‘,6‘-Trihydroxyacetophenone;Phloroacetophenone;Ethanone, 1-(2,4,6-trihydroxyphenyl)-;2\',4\',6\'-Trihydroxyacetophenone Monohydrate;1-(2,4,6-trihydroxyphenyl)ethanone;2-Acetylphloroglucinol;2-Acetylphloroglucinol,THAP;2-Acetylphloroglucinol Monohydrate;1-(2,4,6-Trihydroxyphenyl)ethanone;Phloroacetophenone Monohydrate;2\',4\',6\'-Trihydroxyacetophenone monohydrate;
分子式:C8H8O4
分子量:168.147
精确质量:168.042
Psa:77.76
Logp:1.006
            中文别名:2\',4\',6\'-三羟基乙酰苯一水合物;2,4,6-三羟基苯乙酮;2\',4\',6\'-三羟基苯乙酮一水合物;
英文别名:2,4,6-Trihydroxyacetophenone;2‘,4‘,6‘-Trihydroxyacetophenone;Phloroacetophenone;Ethanone, 1-(2,4,6-trihydroxyphenyl)-;2\',4\',6\'-Trihydroxyacetophenone Monohydrate;1-(2,4,6-trihydroxyphenyl)ethanone;2-Acetylphloroglucinol;2-Acetylphloroglucinol,THAP;2-Acetylphloroglucinol Monohydrate;1-(2,4,6-Trihydroxyphenyl)ethanone;Phloroacetophenone Monohydrate;2\',4\',6\'-Trihydroxyacetophenone monohydrate;
分子式:C8H8O4
分子量:168.147
精确质量:168.042
Psa:77.76
Logp:1.006
编号系统
                                    MDL号:MFCD00149091
EINECS号:207-556-5
                            
            EINECS号:207-556-5
物化性质
                                    外观与性状:淡黄色晶体
密度:1.446 g/cm3
沸点:333.2ºC at 760 mmHg
熔点:219-221°C(lit.)
闪点:169.5ºC
稳定性:Stable at room temperature in closed containers under normal storage and handling conditions.
储存条件:Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
蒸汽压:7.16E-05mmHg at 25°C
                            
            密度:1.446 g/cm3
沸点:333.2ºC at 760 mmHg
熔点:219-221°C(lit.)
闪点:169.5ºC
稳定性:Stable at room temperature in closed containers under normal storage and handling conditions.
储存条件:Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
蒸汽压:7.16E-05mmHg at 25°C
安全信息
                                    RTECS号:AN0528000
安全说明:S26-S36-S24/25
WGK Germany:3
危险类别码:R36/37/38
海关编码:2942000000
危险品标志:Xi
信号词:Warning
危险性防范说明:P261; P305 + P351 + P338
危险标志:GHS07
危险性描述:H315; H319; H335
                   
            
            安全说明:S26-S36-S24/25
WGK Germany:3
危险类别码:R36/37/38
海关编码:2942000000
危险品标志:Xi
信号词:Warning
危险性防范说明:P261; P305 + P351 + P338
危险标志:GHS07
危险性描述:H315; H319; H335
生产方法及用途
                                    用途
用于有机合成、医药中间体和合成新型抗氧剂黄烷酮等。
                            
            用于有机合成、医药中间体和合成新型抗氧剂黄烷酮等。
合成路线
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                            参考文献Morkunas, Marius; Dube, Linda; Goetz, Friedrich; Maier, Martin E. Tetrahedron, 2013 , vol. 69, # 40 p. 8559 - 8563 
上游原料
下游产品
图谱
Predict 1H proton NMR
 
                13C NMR : Predict
 
                1H NMR : Predict
 
                Mass spectrum (electron ionization)
 
                Mass
 
                IR : nujol mull
 
                IR : KBr disc
 
                










