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  • D-(-)-酒石酸二乙酯

    (-)-Diethyl D-tartrate

化合物简介

Diethyl D-(-)-Tartrate is used as a chiral reagent in a host of chemical reactions, suhc as marin toxin and antitumor agent phorboxazole A, or asymmetric syntheses of S,S-dialkyl-substituted sulfoximines.

基本信息

CAS:13811-71-7
中文别名:D(-)-酒石酸二乙酯;D-酒石酸二乙酯;
英文别名:Butanedioic acid, 2,3-dihydroxy-, diethyl ester, [S-(R*,R*)]-;Diethyl D-(-)-tartrate;(2S,3S)-Diethyl 2,3-dihydroxysuccinate;D-(-)-Tartaric Acid Diethyl Ester;Diethyl-D-tartrate;
分子式:C8H14O6
分子量:206.193
精确质量:206.079
Psa:93.06
Logp:-1.1656

编号系统

EINECS号:237-458-8
BRN号:1727143
MDL号:MFCD00064451
PubChem号:24852814

物化性质

外观与性状:白色晶体
密度:1.205
沸点:280ºC
熔点:17ºC
闪点:93ºC
折射率:1.445-1.447
稳定性:Stable under normal temperatures and pressures.
储存条件:Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
蒸汽压:0.000467mmHg at 25°C

安全信息

安全说明:S24/25
危险类别码:R36/37/38
海关编码:29181300
危险品标志:Xi

生产方法及用途

用途
主要用于手性药物、手性中间体的合成及不对称催化领域。

合成路线

上游原料

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图谱

1H NMR : Predict


13C NMR : Predict


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