(3S)-5-[1-(triisopropylsiloxy)-prop-2-(R)-yl]-3-(triethylsiloxy)-hex-5-en-1-ol (3S)-5-[1-(triisopropylsiloxy)-prop-2-(R)-yl]-3-(triethylsiloxy)-hex-5-en-1-ol CAS号880485-35-8分子式、结构式、MSDS、物化性质、用途-化学科研者一站式服务平台

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(3S)-5-[1-(triisopropylsiloxy)-prop-2-(R)-yl]-3-(triethylsiloxy)-hex-5-en-1-ol

化合物简介

基本信息

CAS：880485-35-8
中文别名：
英文别名：(3S,6R)-6-Methyl-5-methylene-3-triethylsilanyloxy-7-triisopropylsilanyloxy-heptan-1-ol;
分子式：C24H52O3Si2
分子量：444.839
精确质量：444.345
Psa：38.69
Logp：7.5337

编号系统

物化性质

安全信息

生产方法及用途

合成路线

158783-85-8
(S)-N-methoxy-N-methyl-3-triisopropylsilanyloxy-2-methylpropionamide
880485-35-8
(3S)-5-[1-(triisopropylsiloxy)-prop-2-(R)-yl]-3-(triethylsiloxy)-hex-5-en-1-ol

参考文献

Paterson, Ian; Coster, Mark J.; Chen, David Y.-K.; Oballa, Renata M.; Wallace, Debra J.; Norcross, Roger D. Organic and Biomolecular Chemistry, 2005, vol. 3, # 13 p. 2399 - 2409 doi: 10.1039/b504146e

上游原料

158783-85-8
(S)-N-methoxy-N-methyl-3-triisopropylsilanyloxy-2-methylpropionamide
199857-59-5
(S)-7,7-diisopropyl-4,8-dimethyl-3-methylene-1,1-bis((1S,2R,3S,5S)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl)-2,6-dioxa-7-sila-1-boranonane

下游产品

862379-38-2
(2R,4S,6S,8S,10S)-(4-(t-butyldimethylsiloxy)-10-hydroxy-10-methyl-8-{2-[1-methyl-2-(triisopropylsiloxy)-ethyl]-allyl}-1,7-dioxaspiro[5.5]undec-2-yl)-acetaldehyde
862379-37-1
(2S,4S,6R,8S,10S)-8-(2-hydroxyethyl)-10-(t-butyldimethylsiloxy)-4-methyl-2-{2-[1-(triisopropylsiloxy)-prop-2-(R)-yl]-allyl}-1,7-dioxaspiro[5.5]undecan-4-ol
862379-34-8
2,2,2-trichloroethyl (2R,4S,6S,8S,10S)-(4-acetoxy-10-hydroxy-10-methyl-8-{2-[1-(triisopropylsiloxy)-prop-2-(R)-yl]-allyl}-1,7-dioxaspiro[5.5]undec-2-yl)-acetate
862379-35-9
2,2,2-trichloroethyl (2R,4S,6S,8S,10S)-(4-acetoxy-8-{2-[1-hydroxy-prop-2-(R)-yl]-allyl}-10-methyl-10-(triethylsiloxy)-1,7-dioxaspiro[5.5]undec-2-yl)-acetate
218798-99-3
2,2,2-trichloroethyl (2R,4S,6S,8S,10S)-(4-acetoxy-10-hydroxy-8-{2-[1-hydroxy-prop-2-(R)-yl]-allyl}-10-methyl-1,7-dioxaspiro[5.5]undec-2-yl)-acetate