(+)-(E)-2-((3aS,4R,5R,6aS)-5-(tert-butyldimethylsilyloxy)-4-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)hexahydropentalen-2(1H)-ylidene)ethyl acetate (+)-(E)-2-((3aS,4R,5R,6aS)-5-(tert-butyldimethylsilyloxy)-4-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)hexahydropentalen-2(1H)-ylidene)ethyl acetate CAS号873949-50-9分子式、结构式、MSDS、物化性质、用途-化学科研者一站式服务平台

化学科研者一站式服务平台

预览

(+)-(E)-2-((3aS,4R,5R,6aS)-5-(tert-butyldimethylsilyloxy)-4-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)hexahydropentalen-2(1H)-ylidene)ethyl acetate

化合物简介

基本信息

CAS：873949-50-9
中文别名：
英文别名：Acetic acid 2-[(3aS,4R,5R,6aS)-5-(tert-butyl-dimethyl-silanyloxy)-4-[(E)-(3S,4S)-3-(tert-butyl-dimethyl-silanyloxy)-4-methyl-oct-1-en-6-ynyl]-hexahydro-pentalen-(2E)-ylidene]-ethyl ester;
分子式：C33H58O4Si2
分子量：574.982
精确质量：574.387
Psa：44.76
Logp：8.9085

编号系统

物化性质

安全信息

生产方法及用途

合成路线

74842-89-0
(+)-(3aS,4R,5R,6aR)-5-hydroxy-4-((3S,4S,E)-3-hydroxy-4-methyl-oct-1-en-6-ynyl)hexahydropentalene-2(1H)-one
873949-50-9
(+)-(E)-2-((3aS,4R,5R,6aS)-5-(tert-butyldimethylsilyloxy)-4-((3S,4S,E)-3-(tert-butyldimethylsilyloxy)-4-methyloct-1-en-6-ynyl)hexahydropentalen-2(1H)-ylidene)ethyl acetate

参考文献

Kramp, Guido J.; Kim, Mikhail; Gais, Hans-Joachim; Vermeeren, Cornelia Journal of the American Chemical Society, 2005, vol. 127, # 50 p. 17910 - 17920 doi: 10.1021/ja0558037