化合物简介
基本信息
CAS：77480-16-1
中文别名：
英文别名：(1S,2R,5R,6R,7R,8S,9S,10R,12S,13S,17R)-5-Ethyl-7,9-dihydroxy-2,6,8,10,12,15,15,17-octamethyl-4,14,16-trioxa-bicyclo[11.3.1]heptadecan-3-one;
分子式：C24H44O6
分子量：428.603
精确质量：428.314
Psa：85.22
Logp：3.7704
编号系统
物化性质
安全信息
生产方法及用途
合成路线
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(1S,2R,4S,5S,9S,10R,13R,14S,15S,17R,19S,20R)-13-Ethyl-17-(4-methoxy-phenyl)-2,4,7,7,10,14,19,20-octamethyl-6,8,12,16,18-pentaoxa-tricyclo[13.3.1.15,9]icosan-11-one
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参考文献
Evans, David A.
Journal of the American Chemical Society, 1998, vol. 120, # 24 p. 5921 - 5942
doi: 10.1021/ja9806128
上游原料
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(1S,2R,4S,5S,9S,10R,13R,14S,15S,17R,19S,20R)-13-Ethyl-17-(4-methoxy-phenyl)-2,4,7,7,10,14,19,20-octamethyl-6,8,12,16,18-pentaoxa-tricyclo[13.3.1.15,9]icosan-11-one
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(R)-2-((4S,5R,6S)-6-{(1S,3R)-3-[(2R,4S,5S,6S)-6-((1S,2R)-2-Hydroxy-1-methyl-butyl)-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-1-methyl-butyl}-2,2,5-trimethyl-[1,3]dioxan-4-yl)-propionic acid
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(R)-2-((4S,5R,6S)-6-((2S,4R)-4-((4S,5S,6R)-6-((2R,3R)-3-(tert-butyldimethylsilyloxy)pentan-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)pentan-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propanoic acid
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(R)-4-Benzyl-3-[(R)-2-((4S,5R,6S)-6-{(1S,3R)-3-[(2R,4S,5S,6R)-6-[(1R,2R)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-butyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-1-methyl-butyl}-2,2,5-trimethyl-[1,3]dioxan-4-yl)-propionyl]-oxazolidin-2-one
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(R)-4-benzyl-3-((R)-2-((4S,5R,6S)-6-((2S,3R,4R)-4-((2R,4S,5S,6R)-6-((2R,3R)-3-((tert-butyldimethylsilyl)oxy)pentan-2-yl)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)-3-hydroxypentan-2-yl)-2,2,5-trimethyl-1,3-dioxan-4-yl)propanoyl)oxazolidin-2-one
下游产品
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(1S,2R,5R,6R,7S,8R,10R,12S,13S,17R)-5-Ethyl-7-hydroxy-2,6,8,10,12,15,15,17-octamethyl-4,14,16-trioxa-bicyclo[11.3.1]heptadecane-3,9-dione
图谱
