4-azido-4-deoxy-1,2:5,6-di-O-isopropylidene-D-glucitol 4-azido-4-deoxy-1,2:5,6-di-O-isopropylidene-D-glucitol CAS号71756-33-7分子式、结构式、MSDS、物化性质、用途-化学科研者一站式服务平台

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4-azido-4-deoxy-1,2:5,6-di-O-isopropylidene-D-glucitol

化合物简介

基本信息

CAS：71756-33-7
中文别名：
英文别名：(1S,2S)-2-Azido-1,2-bis-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-ethanol;
分子式：C12H21N3O5
分子量：287.312
精确质量：287.148
Psa：106.9
Logp：0.78196

编号系统

物化性质

熔点：88 - 89 °C (二异丙醚)

安全信息

生产方法及用途

合成路线

77594-09-3
Acetic acid (2S,3R,4S,5R,6S)-3-acetoxy-5-azido-2-methoxy-6-trityloxymethyl-tetrahydro-pyran-4-yl ester
71756-33-7
4-azido-4-deoxy-1,2:5,6-di-O-isopropylidene-D-glucitol

参考文献

Ogawa, Tomoya; Katano, Kiyoaki; Matsui, Masanao Tetrahedron, 1980, vol. 36, p. 2727 - 2733 doi: 10.1016/0040-4020(80)80148-7

上游原料

77594-09-3
Acetic acid (2S,3R,4S,5R,6S)-3-acetoxy-5-azido-2-methoxy-6-trityloxymethyl-tetrahydro-pyran-4-yl ester
104700-53-0
Methyl 2,3-di-O-acetyl-α-D-galactopyranoside
620173-69-5

下游产品

77646-96-9
1,4-diamino-1,4-dideoxy-2-O-(4'-amino-4'-deoxy-N-propionyl-α-D-glucopyranosyl)-D-glucitol
77594-15-1
Propionic acid (2S,3R,4S,5R,6R)-3-amino-6-[(1S,2R,3S)-2-amino-1-((S)-2-amino-1-hydroxy-ethyl)-3,4-dihydroxy-butoxy]-4,5-bis-benzyloxy-tetrahydro-pyran-2-ylmethyl ester
77594-17-3
Propionic acid (2S,3R,4S,5R,6R)-3-amino-6-((1S,2S,3R,4S)-3-amino-1-aminomethyl-2,4,5-trihydroxy-pentyloxy)-4,5-bis-benzyloxy-tetrahydro-pyran-2-ylmethyl ester
77594-16-2
N-{(2S,3R,4S,5R,6R)-6-[(1S,2R,3S)-2-Amino-1-((S)-2-amino-1-hydroxy-ethyl)-3,4-dihydroxy-butoxy]-4,5-bis-benzyloxy-2-hydroxymethyl-tetrahydro-pyran-3-yl}-propionamide
77594-18-4
N-[(2S,3R,4S,5R,6R)-6-((1S,2S,3R,4S)-3-Amino-1-aminomethyl-2,4,5-trihydroxy-pentyloxy)-4,5-bis-benzyloxy-2-hydroxymethyl-tetrahydro-pyran-3-yl]-propionamide