(1S,3R,4R,5R,6R,7R)-3-(3-acetoxyprop-1(E)-enyl)-4,6-bis(trimethylsiloxy)-5,6-dimethyl-7-ethyl-2,8-dioxabicyclo[3.3.0]octane (1S,3R,4R,5R,6R,7R)-3-(3-acetoxyprop-1(E)-enyl)-4,6-bis(trimethylsiloxy)-5,6-dimethyl-7-ethyl-2,8-dioxabicyclo[3.3.0]octane CAS号536737-91-4分子式、结构式、MSDS、物化性质、用途-化学科研者一站式服务平台

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预览

(1S,3R,4R,5R,6R,7R)-3-(3-acetoxyprop-1(E)-enyl)-4,6-bis(trimethylsiloxy)-5,6-dimethyl-7-ethyl-2,8-dioxabicyclo[3.3.0]octane

化合物简介

基本信息

CAS：536737-91-4
中文别名：
英文别名：Acetic acid (E)-3-((2R,3R,3aR,4R,5R,6aS)-5-ethyl-3a,4-dimethyl-3,4-bis-trimethylsilanyloxy-hexahydro-furo[2,3-b]furan-2-yl)-allyl ester;
分子式：C21H40O6Si2
分子量：444.71
精确质量：444.236
Psa：63.22
Logp：4.476

编号系统

物化性质

安全信息

生产方法及用途

合成路线

536737-63-0
(2RS,3R,4R,5R)-3-[(2R,3R)-2,3-dihydroxy-2-pentyl]-5-(triisopropylsiloxymethyl)-2-methoxy-4-(4-methoxybenzyloxy)-3-methyloxolane
536737-91-4
(1S,3R,4R,5R,6R,7R)-3-(3-acetoxyprop-1(E)-enyl)-4,6-bis(trimethylsiloxy)-5,6-dimethyl-7-ethyl-2,8-dioxabicyclo[3.3.0]octane

参考文献

Eom, Khee Dong; Raman, J. Venkat; Kim, Heejin; Cha, Jin Kun Journal of the American Chemical Society, 2003, vol. 125, # 18 p. 5415 - 5421 doi: 10.1021/ja034332q