(1S,5R,9R,10R,11S,12R,13S)-13-[(1R,2R,3S,5S,6R)-7-aza-2-methoxy-1,5-dimethyl-4,9-dioxa-8-oxo-7-(tert-butyldimethylsilyl)bicyclo[4.3.0]non-3-yloxy]-1-hydroxy-5-(hydroxymethyl)-9-methoxy-7,10,12-trimethyl-4,15-dioxabicyclo[9.3.1]pentadec-7-en-3-one (1S,5R,9R,10R,11S,12R,13S)-13-[(1R,2R,3S,5S,6R)-7-aza-2-methoxy-1,5-dimethyl-4,9-dioxa-8-oxo-7-(tert-butyldimethylsilyl)bicyclo[4.3.0]non-3-yloxy]-1-hydroxy-5-(hydroxymethyl)-9-methoxy-7,10,12-trimethyl-4,15-dioxabicyclo[9.3.1]pentadec-7-en-3-one CAS号439143-49-4分子式、结构式、MSDS、物化性质、用途-化学科研者一站式服务平台

化学科研者一站式服务平台

预览

(1S,5R,9R,10R,11S,12R,13S)-13-[(1R,2R,3S,5S,6R)-7-aza-2-methoxy-1,5-dimethyl-4,9-dioxa-8-oxo-7-(tert-butyldimethylsilyl)bicyclo[4.3.0]non-3-yloxy]-1-hydroxy-5-(hydroxymethyl)-9-methoxy-7,10,12-trimethyl-4,15-dioxabicyclo[9.3.1]pentadec-7-en-3-one

化合物简介

基本信息

CAS：439143-49-4
中文别名：
英文别名：3-(tert-butyl-dimethyl-silanyl)-6-(1-hydroxy-5-hydroxymethyl-9-methoxy-7,10,12-trimethyl-3-oxo-4,15-dioxa-bicyclo[9.3.1]pentadec-7-en-13-yloxy)-7-methoxy-4,7a-dimethyl-tetrahydro-pyrano[3,4-d]oxazol-2-one;
分子式：C33H57NO11Si
分子量：671.891
精确质量：671.37
Psa：142.45
Logp：4.0629

编号系统

物化性质

安全信息

生产方法及用途

合成路线

439143-44-9
2-(6-{(1E)(4S)-5-[(4-methoxyphenyl)methoxy]-2-methyl-4-(tert-butyldimethylsilyloxy)pent-1-enyl}(4S,5R,6R)-2,2,5-trimethyl(1,3-dioxan-4-yl))(2S)propanal
439143-49-4
(1S,5R,9R,10R,11S,12R,13S)-13-[(1R,2R,3S,5S,6R)-7-aza-2-methoxy-1,5-dimethyl-4,9-dioxa-8-oxo-7-(tert-butyldimethylsilyl)bicyclo[4.3.0]non-3-yloxy]-1-hydroxy-5-(hydroxymethyl)-9-methoxy-7,10,12-trimethyl-4,15-dioxabicyclo[9.3.1]pentadec-7-en-3-one

参考文献

Evans, David A.; Hu, Essa; Burch, Jason D.; Jaeschke, Georg Journal of the American Chemical Society, 2002, vol. 124, # 20 p. 5654 - 5655 doi: 10.1021/ja026235n