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  • 环戊二烯基双(三苯基膦)氯化钌(II)

    Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)

化合物简介

Chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium is the organoruthenium half-sandwich compound with formula RuCl(PPh3)2(C5H5). It as an air-stable orange crystalline solid that is used in a variety of organometallic synthetic and catalytic transformations. The compound has idealized Cs symmetry. It is soluble in chloroform, dichloromethane, and acetone.

基本信息

CAS:32993-05-8
中文别名:氯(环戊二烯基)双(三苯膦)钌(Ⅱ);二(三苯基膦)环戊二烯基氯化钌(II);
英文别名:CpRu(PPh3)2Cl;Chlorocyclopentadienylbis(triphenylphosphine)rutenium(II);Chlorocyclopentadienylbis-(triphenylphosphino)-ruthenium;[ClRu(PPh3)2Cp];Chlorocyclopentadienylbis(triphenylphosphine)rutheniuM(II) 5GR;(Ph3P)2(cyclopentadienyl)RuCl;Cyclopentadienylbis(triphenylphosphine)rutheniuM(II) Chloride;chlorocyclopentadienylbis(triphenylphosphine)ruthenium;Cyclopentadienyl;[Cp(PPh3)2RuCl];Cyclopentadienylbis(triphenylphosphine)ruthenium(II) Chloride;Chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium(II);
分子式:C41H35ClP2Ru
分子量:726.187
精确质量:726.095
Psa:27.18
Logp:8.6006

编号系统

MDL号:MFCD00075004

物化性质

熔点:135°C (dec.)(lit.)
水溶解性:可溶

安全信息

安全说明:26-37/39-36/37/39-22
危险类别码:R20/21/22; R36/37/38
WGK Germany:3
危险品标志:Xn

生产方法及用途

合成路线

上游原料

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图谱

1H NMR : Predict


13C NMR : Predict


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