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  • 三氧化硫吡啶

    Pyridine sulfur trioxide

化合物简介

Sulfur trioxide pyridine complex is the compound with the formula C5H5NSO3. It is a colourless solid that dissolves in polar organic solvents. It is the adduct formed from the Lewis base pyridine and the Lewis acid sulfur trioxide. The compound is mainly used as a source of sulfur trioxide, for example in the synthesis of sulfate esters from alcohols:

基本信息

CAS:26412-87-3
中文别名:三氧化硫-吡啶复合物;吡啶-三氧化硫复合物;吡啶三氧化硫;硫磺三氧吡啶络合物;氧化硫吡啶复合物;
英文别名:(DIMETHYLAMINOMETHYL)STYRENE;Active Sulfure Trioxide;sulfur trioxide pyridine;Sulfur Trioxide - Pyridine Complex;PyridineSO3;SO3*pyridine complex;sulfur trioride-pyridine;Sulfur trioxide pyri;VINYLBENZYLDIMETHYLAMINE;sulfur(VI) oxide-pyridine complex;Pyridine - Sulfur Trioxide Complex;N,N-DIMETHYLVINYLBENZYLAMINE;pyridine/sulfur trioxide complex;Sulfur trioxide pyridine complex;sulfur trioxide-pyridine complex;
分子式:C5H5NO3S
分子量:159.163
精确质量:158.999
Psa:96.19
Logp:1.3734

编号系统

BRN号:3704116
MDL号:MFCD00012437
EINECS号:247-683-3

物化性质

外观与性状:白色至米色粉末
沸点:115.3ºC at 760 mmHg
熔点:~160°C
闪点:20ºC
水溶解性:reacts
稳定性:Stable under normal temperatures and pressures.
储存条件:Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from water.
蒸汽压:22.8mmHg at 25°C

安全信息

安全说明:S26-S36/37/39-S45
危险类别码:R22; R34
WGK Germany:3
海关编码:29420000
危险品运输编码:UN 3261 8/PG 2
危险类别:8
包装等级:II
危险品标志:C
危险性防范说明:P280; P305 + P351 + P338; P310
信号词:Danger
危险标志:GHS05, GHS07
危险性描述:H302; H314

生产方法及用途

生产方法
用吡啶与氯磺酸在室温下反应制得。 用作氧化剂及磺化剂。
用途
用作氧化剂及磺化剂。

合成路线

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图谱

Predict 1H proton NMR


13C NMR : Predict


1H NMR : Predict


13C NMR : in D2O


Mass


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