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化合物简介
Tricyclohexylphosphine is the tertiary phosphine with the formula P(C6H11)3. Commonly used as a ligand in organometallic chemistry, it is often abbreviated to PCy3, where Cy stands for cyclohexyl. It is characterized by both high basicity (pKa= 9.7) and a large ligand cone angle (170°).
基本信息
CAS:2622-14-2
中文别名:三环已基磷;三环己基磷;三环己基;
英文别名:triscyclohexylphosphine;Tricyclohexylphosphine;Phosphine,tricyclohexyl;Tricyclohexyl-phosphane;Tricyclohexyl Phosphine;bistricyclohexylphosphine;Tricyclohexylphosphine solution;PCy3;tricyclohexylphosphan;TRICYCLOHEXYL PHOSPHINE;
分子式:C18H33P
分子量:280.428
精确质量:280.232
Psa:13.59
Logp:6.4664
中文别名:三环已基磷;三环己基磷;三环己基;
英文别名:triscyclohexylphosphine;Tricyclohexylphosphine;Phosphine,tricyclohexyl;Tricyclohexyl-phosphane;Tricyclohexyl Phosphine;bistricyclohexylphosphine;Tricyclohexylphosphine solution;PCy3;tricyclohexylphosphan;TRICYCLOHEXYL PHOSPHINE;
分子式:C18H33P
分子量:280.428
精确质量:280.232
Psa:13.59
Logp:6.4664
编号系统
MDL号:MFCD00003853
EINECS号:220-069-2
EINECS号:220-069-2
物化性质
外观与性状:白色至黄色结晶粉末
密度:0.909g/mLat 25°C
沸点:110°C
熔点:81-83°C(lit.)
闪点:48°F
稳定性:Stable at room temperature in closed containers under normal storage and handling conditions.
储存条件:-20ºC
蒸汽压:9.7E-06mmHg at 25°C
密度:0.909g/mLat 25°C
沸点:110°C
熔点:81-83°C(lit.)
闪点:48°F
稳定性:Stable at room temperature in closed containers under normal storage and handling conditions.
储存条件:-20ºC
蒸汽压:9.7E-06mmHg at 25°C
安全信息
安全说明:S26-S36/37-S62-S37/39-S36-S33-S29-S16
WGK Germany:3
危险类别码:R22; R36/37/38
危险品运输编码:UN 2056 3/PG 2
海关编码:2931900090
包装等级:III
危险品标志:Xn
危险标志:GHS02, GHS07, GHS08
信号词:Danger
危险性防范说明:P210; P261; P281; P301 + P310; P305 + P351 + P338; P331
危险性描述:H225; H304; H315; H319; H335 + H336; H361d; H373
WGK Germany:3
危险类别码:R22; R36/37/38
危险品运输编码:UN 2056 3/PG 2
海关编码:2931900090
包装等级:III
危险品标志:Xn
危险标志:GHS02, GHS07, GHS08
信号词:Danger
危险性防范说明:P210; P261; P281; P301 + P310; P305 + P351 + P338; P331
危险性描述:H225; H304; H315; H319; H335 + H336; H361d; H373
生产方法及用途
用途
催化剂,作为配体,用于Buchwald。
催化剂,作为配体,用于Buchwald。
合成路线
上游原料
下游产品
图谱
Predict 1H proton NMR

13C NMR : Predict

1H NMR : Predict

13C NMR : in CDCl3

Mass spectrum (electron ionization)

Mass
