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化合物简介
Solketal is a protected form of glycerol with an isopropylidene acetal group joining two neighboring hydroxyl groups. Solketal contains a chiral center on the center carbon of the glycerol backbone, and so can be purchased as either the racemate or as one of the two enantiomers. Solketal has been used extensively in the synthesis of mono-, di- and triglycerides by ester bond formation. The free hydroxyl groups of solketal can be esterified with a carboxylic acid to form the protected monoglyceride, where the isopropylene group can then be removed using an acid catalyst in aqueous or alcoholic medium. The unprotected diol can then be esterified further to form either the di- or triglyceride.
基本信息
CAS:22323-82-6
中文别名:(S)-丙硼缩水甘油;(S)-(+)-2,3-异亚丙基甘油;(S)-丙酮缩甘油;(S)-(+)-2,2-二甲基-1,3-二氧戊环-4-甲醇;(S)-(+)-甘油醇缩丙酮;(S)-(+)-2,3-氧-亚丙基甘油;D-甘油醇缩丙酮;S-丙酮缩甘油;
英文别名:s-glycerol acetonide;1,2-Isopropylidene-sn-glycerol;(S)-(+)-2,3-O-Isopropylideneglycerol;(S)-(+)-2,2-Dimethyl-1,3-dioxolane-4-methanol;D-1,2-O-isopropylidene-sn-glycerol;(S)-(+)-1,2-Isopropylideneglycerol;D-(+)-1,2-Isopropylideneglycerol;4-hydroxymethyl-2,2-dimethyl-1,3-dioxolane;
分子式:C6H12O3
分子量:132.158
精确质量:132.079
Psa:38.69
Logp:0.1302
中文别名:(S)-丙硼缩水甘油;(S)-(+)-2,3-异亚丙基甘油;(S)-丙酮缩甘油;(S)-(+)-2,2-二甲基-1,3-二氧戊环-4-甲醇;(S)-(+)-甘油醇缩丙酮;(S)-(+)-2,3-氧-亚丙基甘油;D-甘油醇缩丙酮;S-丙酮缩甘油;
英文别名:s-glycerol acetonide;1,2-Isopropylidene-sn-glycerol;(S)-(+)-2,3-O-Isopropylideneglycerol;(S)-(+)-2,2-Dimethyl-1,3-dioxolane-4-methanol;D-1,2-O-isopropylidene-sn-glycerol;(S)-(+)-1,2-Isopropylideneglycerol;D-(+)-1,2-Isopropylideneglycerol;4-hydroxymethyl-2,2-dimethyl-1,3-dioxolane;
分子式:C6H12O3
分子量:132.158
精确质量:132.079
Psa:38.69
Logp:0.1302
编号系统
PubChem号:24854267
MDL号:MFCD00063239
BRN号:80118
EINECS号:244-910-8
RTECS号:JI0400000
MDL号:MFCD00063239
BRN号:80118
EINECS号:244-910-8
RTECS号:JI0400000
物化性质
外观与性状:白色至灰白色晶体
密度:1.07
沸点:82-83ºC (14 mmHg)
闪点:80ºC
折射率:1.433-1.435
稳定性:Stable. Flammable. Incompatible with oxidizing agents.
储存条件:2-8ºC
密度:1.07
沸点:82-83ºC (14 mmHg)
闪点:80ºC
折射率:1.433-1.435
稳定性:Stable. Flammable. Incompatible with oxidizing agents.
储存条件:2-8ºC
安全信息
安全说明:S24/25
海关编码:29329970
海关编码:29329970
生产方法及用途
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图谱
1H NMR : Predict

13C NMR : Predict
