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  • 双(三苯基膦)氯化铵

    Bis(triphenylphosphine)iminium chloride

化合物简介

Bis(triphenylphosphine)iminium chloride is the chemical compound with the formula [(C6H5)3P)2N]Cl, often written [(Ph3P)2N]Cl and abbreviated PPNCl. This colorless salt is a source of the PPN+ cation, which is used to isolate reactive anions. PPN+ is a phosphazene.

基本信息

CAS:21050-13-5
中文别名:双(三苯基正膦基)氯化铵;
英文别名:1,1,1-Triphenyl-N-(triphenylphosphoranylidene)phosphoraniminium chloride;PPNCI;ppncl;Bis(triphenylphosphoranylidene)ammonium chloride;HEXAPHENYLDIPHOSPHAZENIUM CHLORIDE;Hexaphenyldiphosphazenium chloride;
分子式:C36H30ClNP2
分子量:574.031
精确质量:573.154
Psa:35.76
Logp:7.7627

编号系统

EINECS号:244-170-6
PubChem号:24849241
BRN号:4097979
MDL号:MFCD00151523

物化性质

熔点:270-272°C(lit.)
储存条件:2-8°C

安全信息

安全说明:S26; S36; S38; S36/37/39
危险类别码:R36/37/38; R20
WGK Germany:3
海关编码:2931900090
危险品标志:Xi; Xn
危险性描述:H315; H319; H332; H335
危险性防范说明:P261; P305 + P351 + P338
信号词:Warning
危险标志:GHS07

生产方法及用途

用途
相转移催化剂。有机合成。

合成路线

  • 参考文献

    Grung, Knut Eric; Roemming, Christian; Songstad, Jon Acta Chemica Scandinavica, 1989 , vol. 43, # 6 p. 518 - 526

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Predict 1H proton NMR


13C NMR : Predict


1H NMR : Predict


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