化学科研者一站式服务平台
化合物简介
Tetracyanoquinodimethane (TCNQ) is the organic compound with the formula (NC)2CC6H4C(CN)2. This cyanocarbon, a relative of para-quinone, is an electron acceptor that is used to prepare charge transfer salts, which are of interest in molecular electronics.
基本信息
CAS:1518-16-7
中文别名:7,7,8,8-四氰基苯醌二甲烷;7,7,8,8-四氰基对醌二甲烷;7,7\',8,8\'-四氰基对苯二醌二甲烷;7,7,8,8-四氰基对二次甲基苯醌;
英文别名:7,7,8,8-Tetracyanoquinodimethane;2-[4-(dicyanomethylidene)cyclohexa-2,5-dien-1-ylidene]propanedinitrile;7,7\',8,8\'-Tetracyanoquinodimethane;(2,5-Cyclohexadiene-1,4-diylidene)-dimalononitrile;2,2\'-(Cyclohexa-2,5-diene-1,4-diylidene)dimalononitrile;
分子式:C12H4N4
分子量:204.187
精确质量:204.044
Psa:95.16
Logp:0.08232
中文别名:7,7,8,8-四氰基苯醌二甲烷;7,7,8,8-四氰基对醌二甲烷;7,7\',8,8\'-四氰基对苯二醌二甲烷;7,7,8,8-四氰基对二次甲基苯醌;
英文别名:7,7,8,8-Tetracyanoquinodimethane;2-[4-(dicyanomethylidene)cyclohexa-2,5-dien-1-ylidene]propanedinitrile;7,7\',8,8\'-Tetracyanoquinodimethane;(2,5-Cyclohexadiene-1,4-diylidene)-dimalononitrile;2,2\'-(Cyclohexa-2,5-diene-1,4-diylidene)dimalononitrile;
分子式:C12H4N4
分子量:204.187
精确质量:204.044
Psa:95.16
Logp:0.08232
编号系统
RTECS号:GU4850000
BRN号:611604
MDL号:MFCD00011664
EINECS号:216-174-8
BRN号:611604
MDL号:MFCD00011664
EINECS号:216-174-8
物化性质
外观与性状:橙色至绿色结晶粉末
密度:1.358 g/cm3
沸点:254.7ºC at 760 mmHg
熔点:287-289°C (dec.)(lit.)
闪点:99.7ºC
水溶解性:insoluble
稳定性:Stable. Incompatible with strong acids, strong bases, strong reducing agents, strong oxidizing agents.
储存条件:Keep containers tightly closed. Store in a cool, dry area away from incompatible substances.
密度:1.358 g/cm3
沸点:254.7ºC at 760 mmHg
熔点:287-289°C (dec.)(lit.)
闪点:99.7ºC
水溶解性:insoluble
稳定性:Stable. Incompatible with strong acids, strong bases, strong reducing agents, strong oxidizing agents.
储存条件:Keep containers tightly closed. Store in a cool, dry area away from incompatible substances.
安全信息
RTECS号:GU4850000
安全说明:S22-S24/25-S36/37-S26
危险类别码:R20/21/22
WGK Germany:3
海关编码:29269095
危险品运输编码:3276
危险类别:6.1
包装等级:II
危险品标志:Xn
危险性防范说明:P261; P280; P301 + P310; P311
危险标志:GHS06
信号词:Danger
危险性描述:H301 + H311 + H331
安全说明:S22-S24/25-S36/37-S26
危险类别码:R20/21/22
WGK Germany:3
海关编码:29269095
危险品运输编码:3276
危险类别:6.1
包装等级:II
危险品标志:Xn
危险性防范说明:P261; P280; P301 + P310; P311
危险标志:GHS06
信号词:Danger
危险性描述:H301 + H311 + H331
生产方法及用途
合成路线
-
参考文献
Hellrung, Bruno; Balli, Heinz Helvetica Chimica Acta, 1990 , vol. 73, # 1 p. 81 - 85
上游原料
下游产品
图谱
13C NMR : Predict
1H NMR : Predict
ESR : CU(II) COMPLEX OF BIPYRIDINE/TCNQ, POWDER
ESR : CU(II) COMPLEX OF ETHYLEN DIAMINE/TCNQ, POWDER
Mass
IR : KBr disc
IR : nujol mull











