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化合物简介
Indium(I) bromide is a chemical compound of indium and bromine. It is a red crystalline compound that is isostructural with β-TlI and has a distorted rock salt structure. Indium(I) bromide is generally made from the elements, heating indium metal with InBr3. It has been used in the sulfur lamp. In organic chemistry, it has been found to promote the coupling of α, α-dichloroketones to 1-aryl-butane-1,4-diones. Oxidative addition reactions with for example alkyl halides to give alkyl indium halides and with NiBr complexes to give Ni-In bonds are known. It is unstable in water decomposing into indium metal and indium tribromide. When indium dibromide is dissolved in water, InBr is produced as a, presumably, insoluble red precipitate, that then rapidly decomposes.
基本信息
CAS:14280-53-6
中文别名:
英文别名:Faneron;bromofenoxim;Bromfenim;bromoindium;Bromophenoxim;
分子式:BrH2In
分子量:196.738
精确质量:195.838
Psa:0.0
Logp:1.0706
中文别名:
英文别名:Faneron;bromofenoxim;Bromfenim;bromoindium;Bromophenoxim;
分子式:BrH2In
分子量:196.738
精确质量:195.838
Psa:0.0
Logp:1.0706
编号系统
EINECS号:238-172-6
MDL号:MFCD00064630
PubChem号:24869716
MDL号:MFCD00064630
PubChem号:24869716
物化性质
沸点:656ºC
熔点:220ºC
熔点:220ºC
安全信息
安全说明:S26; S36
危险类别码:R20/21/22; R36/37/38
危险品运输编码:UN3260
包装等级:III
危险品标志:Xn
危险性描述:H302 + H312 + H332; H315; H319; H335
危险标志:GHS07
危险性防范说明:P261; P280; P305 + P351 + P338
信号词:Warning
危险类别码:R20/21/22; R36/37/38
危险品运输编码:UN3260
包装等级:III
危险品标志:Xn
危险性描述:H302 + H312 + H332; H315; H319; H335
危险标志:GHS07
危险性防范说明:P261; P280; P305 + P351 + P338
信号词:Warning
生产方法及用途
合成路线
-
参考文献
Journal of Chemical Physics, , vol. 74, # 4 p. 2287 - 2292




