化学科研者一站式服务平台


  • D-γ-Tocotrienol

    γ-tocotrienol

化合物简介

γ-Tocotrienol (or gamma-Tocotrienol) is one of the four types of tocotrienol, a type of vitamin E. ; Vitamin E exists in nature in eight forms, each of which consists of a head section joined to either a saturated (phytyl) or an unsaturated (farnesyl) tail. The four compounds with the saturated tails are the tocopherols, and the four compounds with the unsaturated tails are the tocotrienols. There are four unique dihydrocoumarin head sections, distinguished by one of four substitution patterns and designated as α, β, γ, or δ. The alpha- forms are distinguished by their three substituted methyl groups and the delta- forms by their one substituted methyl group. The beta- and gamma- forms both have two substituted methyl groups, although at different structural positions (5,8-dimethyl and 7,8-dimethyl, respectively), making both beta / gamma tocotrienol as well as the beta / gamma tocopherol pairs of stereoisomer.

基本信息

CAS:14101-61-2
中文别名
英文别名:gamma-tocotrienol;(2R)-2,7,8-trimethyl-2-[(3E,7E)-4,8,12-trimethyltrideca-3,7,11-trienyl]-3,4-dihydrochromen-6-ol;BOC-N-methyl-2-napthylalanine;
分子式:C28H42O2
分子量:410.632
精确质量:410.318
Psa:29.46
Logp:8.2921

编号系统

UNII:185QAE24TR

物化性质

密度:0.964g/cm3
沸点:530.8ºC at 760mmHg
闪点:218.4ºC
折射率:1.523
储存条件:-20ºC
蒸汽压:6.98E-12mmHg at 25°C

安全信息

生产方法及用途

合成路线

  • 参考文献

    Couladouros, Elias A.; Moutsos, Vassilios I.; Lampropoulou, Maria; Little, James L.; Hyatt, John A. Journal of Organic Chemistry, 2007, vol. 72, # 18 p. 6735 - 6741 doi: 10.1021/jo0705418

上游原料

下游产品

图谱

1H NMR : Predict


13C NMR : Predict


加载中...