Hafnium tetrabromide is the inorganic compound with the formula HfBr4. It is the most common bromide of hafnium. It is a colorless, diamagnetic moisture sensitive solid that sublimes in vacuum. It adopts a structure very similar to that of zirconium tetrabromide, featuring tetrahedral Hf centers, in contrast to the polymeric nature of hafnium tetrachloride.

CAS：13777-22-5
中文别名：
英文别名：hafnium bromide;EINECS 237-416-9;HfBr4;Hafnium tetrabromide;
分子式：Br4Hf
分子量：498.106
精确质量：495.62
Psa：0.0
Logp：3.3824

EINECS号：237-416-9

熔点：424ºC

安全说明：S26; S27; S36/37/39; S45
危险类别码：R34
危险品运输编码：UN 1759 8/PG 2
危险品标志：C

生产方法
将5g二氧化铪与15g的干燥糖炭充分混合,置于石墨舟中,将石墨舟放于硼硅酸玻璃管中。将被溴所饱和的纯氮气通入氧化铪中,同时加热至700～800℃。产物经三次升华进行精制,在干燥氮气流中将玻璃管熔封。收量为11g。