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  • 三氟代氧化钒

    Vanadium(V) Trifluoride Oxide

化合物简介

Vanadium(V) oxytrifluoride is a chemical compound with the formula VOF3. It is one of several vanadium(V) oxyhalides. Characteristic of early metal fluorides, the structure is polymeric in the solid state. The solid adopts a layered structure but upon evaporation, the species becomes dimeric. In contrast VOCl3 and VOBr3 remain tetrahedral in all states, being volatile liquids at room temperature.

基本信息

CAS:13709-31-4
中文别名
英文别名:Vanadium(V) trifluoride oxide;VANADIUM OXYTRIFLUORIDE;
分子式:F3OV
分子量:123.936
精确质量:123.934
Psa:17.07
Logp:1.1418

编号系统

MDL号:MFCD00042555
PubChem号:24864853
EINECS号:237-250-7

物化性质

密度:2.45
沸点:480 °C
熔点:300 °C

安全信息

安全说明:S26-S36/37/39-S45
WGK Germany:3
危险类别码:R20/21/22; R32; R34
危险品运输编码:UN 3260 8/PG 2
危险类别:6.1
包装等级:II
危险品标志:C; Xi
危险性防范说明:P280; P305 + P351 + P338; P310
危险性描述:H302 + H312 + H332; H314
补充危害声明:与酸接触会释放有毒气体。
危险标志:GHS05, GHS07
信号词:Danger

生产方法及用途

用途
三氟氧钒 (VO

合成路线

  • 参考文献

    V: MVol.B1, 90, page 243 - 246 Dehnicke, K. (Angew. Chem. 77 (1965) 22/9)

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