化合物简介
基本信息
CAS：1351395-53-3
中文别名：
英文别名：
分子式：C25H31NO6
分子量：441.517
精确质量：441.215
Psa：105.09
Logp：3.7056
编号系统
物化性质
熔点：107 - 110 °C (甲醇)
安全信息
生产方法及用途
合成路线
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(2Z,4Z)-N-((E)-3-((3S,5R,8S,9S)-8-((tert-butyldimethylsilyl)oxy)-14-hydroxy-1-oxo-3,4,5,6,7,8,9,10-octahydro-1H-5,9-epoxybenzo[c][1]oxacyclododecin-3-yl)prop-1-en-1-yl)hepta-2,4-dienamide
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参考文献
Palimkar, Sanjay S.; Uenishi, Jun'Ichi; Ii, Hiromi
Journal of Organic Chemistry, 2012, vol. 77, # 1 p. 388 - 399
doi: 10.1021/jo2019762
上游原料
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(2Z,4Z)-N-((E)-3-((3S,5R,8S,9S)-8-((tert-butyldimethylsilyl)oxy)-14-hydroxy-1-oxo-3,4,5,6,7,8,9,10-octahydro-1H-5,9-epoxybenzo[c][1]oxacyclododecin-3-yl)prop-1-en-1-yl)hepta-2,4-dienamide
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(3S,5R,8S,9S)-14-(benzyloxy)-3-(2-(benzyloxy)ethyl)-8-((tert-butyldimethylsilyl)oxy)-3,4,5,6,7,8,9,10-octahydro-1H-5,9-epoxybenzo[c][1]oxacyclododecin-1-one
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(3S,5R,8S,9S)-8-((tert-butyldimethylsilyl)oxy)-14-hydroxy-3-(2-hydroxyethyl)-3,4,5,6,7,8,9,10-octahydro-1H-5,9-epoxybenzo[c][1]oxacyclododecin-1-one
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(3S,5R,8S,9S)-8-((tert-butyldimethylsilyl)oxy)-3-(2-hydroxyethyl)-1-oxo-3,4,5,6,7,8,9,10-octahydro-1H-5,9-epoxybenzo[c][1]oxacyclododecin-14-yl acetate
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(3R,5R,8S,9S)-8-((tert-butyldimethylsilyl)oxy)-1-oxo-3-(2-oxoethyl)-3,4,5,6,7,8,9,10-octahydro-1H-5,9-epoxybenzo[c][1]oxacyclododecin-14-yl acetate
下游产品
图谱
