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(2S,4R,6R,8R,9S)-2-<(2RS,3RS,5R)-2-acetoxy-8-<(tert-butyldimethylsilyl)oxy>-3,5-dimethyl-3-(phenylsulfonyl)-6(E)-octenyl>-4-<(tert-butyldiphenylsilyl)oxy>-8,9-dimethyl-1,7-dioxaspiro<5.5>undecane
化合物简介
基本信息
CAS:104996-40-9
中文别名:
英文别名:(2S,4R,6R,8R,9S)-2-{(2RS,3RS,5R)-2-acetoxy-8-[(tert-butyldimethylsilyl)oxy]-3,5-dimethyl-3-(phenylsulfonyl)-6(E)-octenyl}-4-[(tert-butyldiphenylsilyl)oxy]-8,9-dimethyl-1,7-dioxaspiro[5.5]undecane;Acetic acid (E)-(1S,2R,4R)-2-benzenesulfonyl-7-(tert-butyl-dimethyl-silanyloxy)-1-[(2R,4R,6R,8R,9S)-4-(tert-butyl-diphenyl-silanyloxy)-8,9-dimethyl-1,7-dioxa-spiro[5.5]undec-2-ylmethyl]-2,4-dimethyl-hept-5-enyl ester;
分子式:C51H76O8SSi2
分子量:905.38
精确质量:904.48
Psa:105.74
Logp:11.8813
中文别名:
英文别名:(2S,4R,6R,8R,9S)-2-{(2RS,3RS,5R)-2-acetoxy-8-[(tert-butyldimethylsilyl)oxy]-3,5-dimethyl-3-(phenylsulfonyl)-6(E)-octenyl}-4-[(tert-butyldiphenylsilyl)oxy]-8,9-dimethyl-1,7-dioxaspiro[5.5]undecane;Acetic acid (E)-(1S,2R,4R)-2-benzenesulfonyl-7-(tert-butyl-dimethyl-silanyloxy)-1-[(2R,4R,6R,8R,9S)-4-(tert-butyl-diphenyl-silanyloxy)-8,9-dimethyl-1,7-dioxa-spiro[5.5]undec-2-ylmethyl]-2,4-dimethyl-hept-5-enyl ester;
分子式:C51H76O8SSi2
分子量:905.38
精确质量:904.48
Psa:105.74
Logp:11.8813
编号系统
物化性质
安全信息
生产方法及用途
合成路线
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参考文献
Barrett; Carr; Attwood; et al. Journal of Organic Chemistry, 1986, vol. 51, # 25 p. 4840 - 4856 doi: 10.1021/jo00375a017