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化合物简介
Tris(acetonitrile)cyclopentadienylruthenium hexafluorophosphate is an organoruthenium compound with the formula [(C5H5)Ru(NCCH3)3]PF6, abbreviated [CpRu(NCMe)3]PF6. It is a yellow-brown solid that is soluble in polar organic solvents. The compound is a salt consisting of the hexafluorophosphate anion and the cation [CpRu(NCMe)3]+. In coordination chemistry, it is used as a source of RuCp+ for further derivitization. In organic synthesis, it is a homogeneous catalyst. It enables C-C bond formation and promotes cycloadditions. The cyclopentadienyl ligand (Cp) is bonded in an η5 manner to the Ru(II) center.
基本信息
CAS:80049-61-2
中文别名:三(乙腈基)环戊二烯基钌六氟磷酸;
英文别名:
分子式:C11H14F6N3PRu
分子量:434.283
精确质量:434.987
Psa:84.96
Logp:5.99354
中文别名:三(乙腈基)环戊二烯基钌六氟磷酸;
英文别名:
分子式:C11H14F6N3PRu
分子量:434.283
精确质量:434.987
Psa:84.96
Logp:5.99354
编号系统
MDL号:MFCD02684569
物化性质
储存条件:Refrigerator (+4ºC)
安全信息
危险品标志:Xi
生产方法及用途
合成路线
上游原料
下游产品
图谱
13C NMR : Predict

1H NMR : Predict
