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化合物简介
N-Methylmorpholine N-oxide (more correctly 4-methylmorpholine 4-oxide), NMO or NMMO is an organic compound. This heterocyclic amine oxide and morpholine derivative is used in organic chemistry as a co-oxidant and sacrificial catalyst in oxidation reactions for instance in osmium tetroxide oxidations and the Sharpless asymmetric dihydroxylation or oxidations with TPAP. NMO is commercially supplied both as a monohydrate C5H11NO2·H2O and as the anhydrous compound. The monohydrate is used as a solvent for cellulose in the Lyocell process to produce cellulose fibers.
基本信息
CAS:7529-22-8
中文别名:4-甲基吗啉-N-氧化物;N-甲基氧化吗啉;N-甲基吗啉-N-氧化物;4-甲基吗啡-N-氧化物;N-甲基吗啉氧化物;
英文别名:4-Methylmorpholine N-Oxide;4-Methylmorpholine 4-oxide;
分子式:C5H11NO2
分子量:117.146
精确质量:117.079
Psa:38.66
Logp:-0.0802
中文别名:4-甲基吗啉-N-氧化物;N-甲基氧化吗啉;N-甲基吗啉-N-氧化物;4-甲基吗啡-N-氧化物;N-甲基吗啉氧化物;
英文别名:4-Methylmorpholine N-Oxide;4-Methylmorpholine 4-oxide;
分子式:C5H11NO2
分子量:117.146
精确质量:117.079
Psa:38.66
Logp:-0.0802
编号系统
MDL号:MFCD00005947
物化性质
外观与性状:无色至略黄色透明液体
密度:1.14 g/cm3
沸点:118-119ºC
熔点:180-184ºC
闪点:118-119ºC
折射率:n20/D 1.43
稳定性:Stable at room temperature in closed containers under normal storage and handling conditions.
储存条件:Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Refrigerator (approx 4ºC). Store protected from moisture.
密度:1.14 g/cm3
沸点:118-119ºC
熔点:180-184ºC
闪点:118-119ºC
折射率:n20/D 1.43
稳定性:Stable at room temperature in closed containers under normal storage and handling conditions.
储存条件:Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Refrigerator (approx 4ºC). Store protected from moisture.
安全信息
安全说明:S26-S36/37
危险类别码:R36/37/38
WGK Germany:1
海关编码:2934999090
危险品标志:Xi
危险性描述:H315; H319; H335
信号词:Warning
危险性防范说明:P261; P305 + P351 + P338
危险标志:GHS07
危险类别码:R36/37/38
WGK Germany:1
海关编码:2934999090
危险品标志:Xi
危险性描述:H315; H319; H335
信号词:Warning
危险性防范说明:P261; P305 + P351 + P338
危险标志:GHS07
生产方法及用途
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图谱
13C NMR : Predict

1H NMR : Predict

Mass spectrum (electron ionization)
