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  • 5,12:6,11:13,16:14,15-四乙桥三环[8.2.2.24,7]十六碳-1(12),4,6,10,13,15-六烯

    <2.2.2.2.2.2>(1,2,3,4,5,6)cyclophane

化合物简介

[2.2.2.2.2.2]( 1,2,3,4,5,6)Cyclophane or superphane is a 6-fold bridged cyclophane with all arene positions in the benzene dimer taken up by ethylene spacers. The compound has been of some scientific interest as a model for testing aromaticity and was first synthesised by Boekelheide in 1979. Superphane is the base compound for a large group of derivatives with structural variations. The analogs with 2 to 5 bridges are also known compounds. The benzene rings have been replaced by other aromatic units, such as those based on ferrocene or stabilized cyclobutadiene. Numerous derivatives are known with variations in the type and length of the bridging units.

基本信息

CAS:60144-50-5
中文别名
英文别名:[2.2.2.2.2.2](1,2,3,4,5,6)Cyclophane;<2.2.2.2.2.2>(1,2,3,4,5,6)-Cyclophan;Superphane;heptacyclo[16.6.0.02,9.05,22.06,13.010,17.014,21]tetracosa-1,5,9,13,17,21-hexaene (non-preferred name);[26]-(1,2,3,4,5,6)-cyclophane;
分子式:C24H24
分子量:312.447
精确质量:312.188
Psa:0.0
Logp:3.9648

编号系统

物化性质

密度:1.265g/cm3
沸点:380.6ºC at 760 mmHg
闪点:200.4ºC
折射率:1.723

安全信息

生产方法及用途

合成路线

上游原料

下游产品

图谱

13C NMR : Predict


1H NMR : Predict


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