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化合物简介
Perchloromethyl mercaptan is the organosulfur compound with the formula [[CCl3SCl]]. It is mainly used as an intermediate for the synthesis of dyes and fungicides (captan, folpet). It is a colorless oil, although commercial samples are yellowish. It is insoluble in water but soluble in organic solvents. It has a foul, unbearable, acrid odor. Perchloromethyl mercaptan is the original name. The most common name is trichloromethanesulfenyl chloride, because the compound is a sulfenyl chloride, not a mercaptan.
基本信息
CAS:594-42-3
中文别名:全氯甲硫醇;
英文别名:Methanesulfenyl chloride,trichloro;Perchloromethyl mercaptan;(Trichloromethane)sulfenyl chloride;trichloromethanesulphenyl chloride;trichloromethyl hypochlorothioite;Perchlormethylmerkaptan;Perchloromethanethiol;trichloromethyl-sulfenyl chloride;Methanesulfenyl chloride, trichloro-;Clairsit;
分子式:CCl4S
分子量:185.888
精确质量:183.847
Psa:25.3
Logp:3.2011
中文别名:全氯甲硫醇;
英文别名:Methanesulfenyl chloride,trichloro;Perchloromethyl mercaptan;(Trichloromethane)sulfenyl chloride;trichloromethanesulphenyl chloride;trichloromethyl hypochlorothioite;Perchlormethylmerkaptan;Perchloromethanethiol;trichloromethyl-sulfenyl chloride;Methanesulfenyl chloride, trichloro-;Clairsit;
分子式:CCl4S
分子量:185.888
精确质量:183.847
Psa:25.3
Logp:3.2011
编号系统
MDL号:MFCD00059474
EINECS号:209-840-4
EINECS号:209-840-4
物化性质
外观与性状:一种黄色油性液体带有一种攻击性的气味
密度:1.7g/mLat 25°C(lit.)
沸点:146-148°C(lit.)
熔点:-44ºC
折射率:n20/D 1.537(lit.)
稳定性:Mildly decomposed by moist air.
储存条件:库房通风低温干燥,与食品分开储运
蒸汽密度:6.41 (vs air)
蒸汽压:2.02 psi ( 20 °C)
密度:1.7g/mLat 25°C(lit.)
沸点:146-148°C(lit.)
熔点:-44ºC
折射率:n20/D 1.537(lit.)
稳定性:Mildly decomposed by moist air.
储存条件:库房通风低温干燥,与食品分开储运
蒸汽密度:6.41 (vs air)
蒸汽压:2.02 psi ( 20 °C)
安全信息
RTECS号:PB0370000
安全说明:S26-S36/37/39-S45-S7/9-S28A-S25-S61
危险类别码:R21; R25; R26; R34
WGK Germany:3
危险品运输编码:UN 1670 6.1/PG 1
海关编码:2930909090
危险类别:6.1(a)
包装等级:I
危险品标志:T+
危险标志:GHS05, GHS06
危险性描述:H301 + H311; H314; H330
信号词:Danger
危险性防范说明:P260; P280; P284; P301 + P310; P305 + P351 + P338; P310
安全说明:S26-S36/37/39-S45-S7/9-S28A-S25-S61
危险类别码:R21; R25; R26; R34
WGK Germany:3
危险品运输编码:UN 1670 6.1/PG 1
海关编码:2930909090
危险类别:6.1(a)
包装等级:I
危险品标志:T+
危险标志:GHS05, GHS06
危险性描述:H301 + H311; H314; H330
信号词:Danger
危险性防范说明:P260; P280; P284; P301 + P310; P305 + P351 + P338; P310
生产方法及用途
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上游原料
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图谱
13C NMR : Predict

Mass spectrum (electron ionization)
