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化合物简介

Mucobromic acid is an organic compound that consists of a dibrominated alkene with aldehyde and carboxylic acid functional groups. It easily tautomerizes to a furanone hemiacetal form. This compound, and the analogous mucochloric acid (CAS #87-56-9), form the group of known mucohalic acids. The bromide appears to behave similarly to the more heavily studied chloride.

基本信息

CAS:488-11-9
中文别名:2,3-二溴-2-丁烯醛酸;二溴代丁烯醛酸;2,3-二溴丁烯醛酸;2,3-二溴-4-氧代-2-丁烯酸;2,3-二溴-2—丁烯醛醛;糠溴酸;
英文别名:Bromomucic acid;DIBROMOALDEHYDOACRYLIC ACID;(Z)-2,3-dibromo-4-oxobut-2-enoic acid;Dibromomalealdehydic acid;2,3-Dibromomalealdehydic acid;Mucobromsaeure;MucobromicAcid;2,3-dibromo-4-oxo-cis-crotonic acid;Mucobromicacid;2,3-Dibrom-4-oxo-cis-crotonsaeure;Dibromo maleic monaldehyde;Malealdehydic acid,dibromo;(2Z)-2,3-dibromo-4-oxobut-2-enoic acid;
分子式:C4H2Br2O3
分子量:257.865
精确质量:255.837
Psa:54.37
Logp:1.2713

编号系统

MDL号:MFCD00063745

物化性质

外观与性状:白色晶体
密度:2.43 g/cm3
沸点:321.8ºC at 760 mmHg
熔点:120-124°C(lit.)
闪点:148.4ºC
稳定性:Stable under normal temperatures and pressures.
储存条件:Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area.
蒸汽压:5.99E-05mmHg at 25°C

安全信息

安全说明:S26-S36/37/39-S45
危险类别码:R34
WGK Germany:3
危险品运输编码:UN 3261 8/PG 2
海关编码:29183000
危险类别:8
包装等级:III
危险品标志:C

生产方法及用途

用途
糠溴酸为用途很广的有机合成中间体,在医药工业上可用于合成磺胺类药物。

合成路线

上游原料

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图谱

13C NMR : Predict


1H NMR : Predict


Mass spectrum (electron ionization)


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