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化合物简介

Retene, methyl isopropyl phenanthrene or 1-methyl-7-isopropyl phenanthrene, C18H18, is a polycyclic aromatic hydrocarbon present in the coal tar fraction, boiling above 360 °C. It occurs naturally in the tars obtained by the distillation of resinous woods. It crystallizes in large plates, which melt at 98.5 °C and boil at 390 °C. It is readily soluble in warm ether and in hot glacial acetic acid. Sodium and boiling amyl alcohol reduce it to a tetrahydroretene, whilst if it be heated with phosphorus and hydriodic acid to 260 °C, a dodecahydride is formed. Chromic acid oxidizes it to retene quinone, phthalic acid and acetic acid. It forms a picrate which melts at 123-124 °C.

基本信息

CAS:483-65-8
中文别名:1-甲基-7-异丙基菲;7-異丙-1-甲菲;
英文别名:methyl-7-isopropylphen-anthrene;7-isopropyl-1-methyl-phenanthrene;1-METHYL-7-ISOPROPYLPHENANTHRENE;1-methyl-7-isopropylphenathrene;Reten;Phenanthrene, 1-methyl-7-(1-methylethyl)-;1-methyl-7-methylethyl-phenanthrene;Methylisopropylphenanthrene;7-Isopropyl-1-methyl-phenanthren;
分子式:C18H18
分子量:234.336
精确质量:234.141
Psa:0.0
Logp:5.4248

编号系统

UNII:0W2D2E1P9Q

物化性质

外观与性状:米色片
密度:1.046 g/cm3
沸点:208°C10mm Hg(lit.)
熔点:95-97°C(lit.)
闪点:177.8ºC
折射率:1.642
稳定性:Stable. Incompatible with strong oxidizing agents.
蒸汽压:5.34E-06mmHg at 25°C

安全信息

WGK Germany:3

生产方法及用途

合成路线

  • 参考文献

    Orcutt; Bogert Journal of the American Chemical Society, 1941 , vol. 63, p. 127,129 Full Text Show Details Brandt New Zealand J. Sci. Technol., 1952 , vol. 34, p. 46,47 Full Text Show Details Uota J. Dep. Agric. Kyushu Univ., 1937 , vol. 5, p. 117,147, 148 Full Text Show Details Brandt New Zealand J. Sci. Technol., 1938 , vol. 20, p. 8,11, 13, 14

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图谱

13C NMR : Predict


1H NMR : Predict


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