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化合物简介
Diphenyl-2-pyridylphosphine is an organophosphorus compound with the formula P(C6H5)2(2-C5H4N). It is the most widely used mono-pyridylphosphine ligand. Other mono-pyridylphosphines ligands (3-, 4-) are not common in chemical literature; however, tris-pyridylphosphines have been thoroughly investigated as ligands in transition metal complexes used for catalysis. Pyridylphosphines, including diphenyl-2-pyridylphosphine, may bind transition metals as monodentate or bidentate ligands4. Diphenyl-2-pyridylphosphine behaves as a P-bound monodentate ligand, or a P,N-bound bidentate ligand. Diphenyl-2-pyridylphosphine is a sought after ligand for its ability to relay protons to transition metals such as palladium(II) in homogeneous catalysis.
基本信息
CAS:37943-90-1
中文别名:二苯基-2-吡啶基膦;2-吡啶基二苯基膦;二苯基-2-吡啶磷;2-二苯基膦基吡啶;
英文别名:2-(Diphenylphosphino)pyridine;2-(Diphenylphosphino)pyridine 2-Pyridyldiphenylphosphine Diphenyl(2-pyridinyl)phosphine;diphenyl(pyridin-2-yl)phosphane;
分子式:C17H14NP
分子量:263.274
精确质量:263.086
Psa:26.48
Logp:2.8398
中文别名:二苯基-2-吡啶基膦;2-吡啶基二苯基膦;二苯基-2-吡啶磷;2-二苯基膦基吡啶;
英文别名:2-(Diphenylphosphino)pyridine;2-(Diphenylphosphino)pyridine 2-Pyridyldiphenylphosphine Diphenyl(2-pyridinyl)phosphine;diphenyl(pyridin-2-yl)phosphane;
分子式:C17H14NP
分子量:263.274
精确质量:263.086
Psa:26.48
Logp:2.8398
编号系统
MDL号:MFCD00192108
物化性质
外观与性状:黄色至橙色结晶粉末
沸点:377.5ºC at 760 mmHg
熔点:82-84°C (dec.)(lit.)
闪点:182.1ºC
沸点:377.5ºC at 760 mmHg
熔点:82-84°C (dec.)(lit.)
闪点:182.1ºC
安全信息
安全说明:S26-S36
WGK Germany:3
危险类别码:R36/37/38
海关编码:2933399090
危险品标志:Xi
危险性描述:H315; H319; H335; H413
危险标志:GHS07
危险性防范说明:P261; P305 + P351 + P338
信号词:Warning
WGK Germany:3
危险类别码:R36/37/38
海关编码:2933399090
危险品标志:Xi
危险性描述:H315; H319; H335; H413
危险标志:GHS07
危险性防范说明:P261; P305 + P351 + P338
信号词:Warning
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Predict 1H proton NMR
