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化合物简介

Bialaphos is a natural herbicide produced by the bacteria Streptomyces hygroscopicus and Streptomyces viridochromogenes. Bialaphos is a protoxin and nontoxic as is. When it is metabolized by the plant, the glutamic acid analog glufosinate is released which inhibits glutamine synthetase. This results in the accumulation of ammonium and disruption of primary metabolism.

基本信息

CAS:35597-43-4
中文别名:双丙氨酰膦;
英文别名:(2S)-2-amino-4-(hydroxymethylphosphinyl)butanoyl-L-alanyl-L-alanine;bialaphos;(2S)-2-amino-4-[hydroxy(methyl)phosphinoyl]butyryl-L-alanyl-L-alanine;Bilanafos [ISO];L-Alanine,4-(hydroxymethylphosphinyl)-L-2-aminobutanoyl-L-alanyl;acide diprogulique;Bialaphos;Antibiotic SF 1293;Phosphinothricylalanylalanine;Bilanafos;(2S)-2-[[(2S)-2-[[(2S)-2-amino-4-[hydroxy(methyl)phosphoryl]butanoyl]amino]propanoyl]amino]propanoic acid;
分子式:C11H22N3O6P
分子量:323.283
精确质量:323.125
Psa:182.29
Logp:-0.2106

编号系统

UNII:7488PCM6I2

物化性质

密度:1.33g/cm3
沸点:793.2ºC at 760 mmHg
熔点:159-161ºC
闪点:433.5ºC
折射率:1.517
储存条件:Store dry at -4ºC

安全信息

安全说明:S26; S36
危险类别码:R20/21/22
危险品标志:Xn

生产方法及用途

合成路线

上游原料

下游产品

图谱

13C NMR : Predict


1H NMR : Predict


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