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化合物简介
Vanadyl acetylacetonate is the chemical compound with the formula VO(C5H7O2)2. This blue-green coordination complex consists of the vanadyl group, VO2+, bound to two acetylacetonate anions, acac−. Like other charge-neutral acetylacetonates, this complex is soluble in organic solvents.
基本信息
CAS:3153-26-2
中文别名:乙酰丙酮钒;乙酰丙酮氧钒;双(乙酰丙酮)氧化钒(IV);双(2,4-戊二酮酸)合氧化钒(IV);双(2,4-戊二酮酸);
英文别名:Acetylacetone Vanadium(IV)oxy Salt;Vanadium, oxobis(2,4-pentanedionato-O,O‘)-, (SP-5-21)-;VO(acac)2;bis(acetylacetonate)oxovanadium;VANADYL PENTANEDIONATE;Vanadyl(IV) acetylacetonate;VANANDEYLACETYLACETONATE;VANADYL ACETYLACETONE;vanadium di(acetylacetonate);vanadium(IV)oxyacetylacetonate;V(IV)-oxyacetylacetonate;Vanadium(IV)-oxy acetylacetonate;Vanadylacetylacetonate;Vanadyl acetylaceton;Bis(2,4-pentanedionato)vanadium(IV) Oxide;Vanadyl Acetylacetonate;Vanadium oxyacetoacetonate;oxobis(2,4-pentanedionato)vanadium(IV);Vanadium(IV)oxy Acetylacetonate;VO(acac)2 (Vanadium(IV)-oxy acetylacetonate;VANADYL 2,4-PENTANEDIONATE;VANADIUMOXY ACETYLACETONATE;bis(acetylacetonato)oxovanadium;Vanadium(IV)oxy Acetyla;
分子式:C10H14O5V
分子量:265.157
精确质量:265.028
Psa:69.67
Logp:1.8014
中文别名:乙酰丙酮钒;乙酰丙酮氧钒;双(乙酰丙酮)氧化钒(IV);双(2,4-戊二酮酸)合氧化钒(IV);双(2,4-戊二酮酸);
英文别名:Acetylacetone Vanadium(IV)oxy Salt;Vanadium, oxobis(2,4-pentanedionato-O,O‘)-, (SP-5-21)-;VO(acac)2;bis(acetylacetonate)oxovanadium;VANADYL PENTANEDIONATE;Vanadyl(IV) acetylacetonate;VANANDEYLACETYLACETONATE;VANADYL ACETYLACETONE;vanadium di(acetylacetonate);vanadium(IV)oxyacetylacetonate;V(IV)-oxyacetylacetonate;Vanadium(IV)-oxy acetylacetonate;Vanadylacetylacetonate;Vanadyl acetylaceton;Bis(2,4-pentanedionato)vanadium(IV) Oxide;Vanadyl Acetylacetonate;Vanadium oxyacetoacetonate;oxobis(2,4-pentanedionato)vanadium(IV);Vanadium(IV)oxy Acetylacetonate;VO(acac)2 (Vanadium(IV)-oxy acetylacetonate;VANADYL 2,4-PENTANEDIONATE;VANADIUMOXY ACETYLACETONATE;bis(acetylacetonato)oxovanadium;Vanadium(IV)oxy Acetyla;
分子式:C10H14O5V
分子量:265.157
精确质量:265.028
Psa:69.67
Logp:1.8014
编号系统
EINECS号:221-590-8
物化性质
外观与性状:绿色至蓝色-绿色结晶粉末
密度:1,4 g/cm3
沸点:140°C 13mm
熔点:235°C (dec.)(lit.)
闪点:79 °C
水溶解性:practically insoluble
稳定性:Stable, but air sensitive. May discolour upon exposure to air. Incompatible with strong oxidizing agents.
储存条件:Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
密度:1,4 g/cm3
沸点:140°C 13mm
熔点:235°C (dec.)(lit.)
闪点:79 °C
水溶解性:practically insoluble
稳定性:Stable, but air sensitive. May discolour upon exposure to air. Incompatible with strong oxidizing agents.
储存条件:Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
安全信息
安全说明:S22; S26; S36; S36/37/39
WGK Germany:3
危险类别码:R20/21/22; R36/37/38
危险品运输编码:3285
海关编码:29420000
危险类别:6.1
包装等级:III
危险品标志:Xn
危险性描述:H302; H315; H319; H335
危险性防范说明:P261; P305 + P351 + P338
信号词:Warning
危险标志:GHS07
WGK Germany:3
危险类别码:R20/21/22; R36/37/38
危险品运输编码:3285
海关编码:29420000
危险类别:6.1
包装等级:III
危险品标志:Xn
危险性描述:H302; H315; H319; H335
危险性防范说明:P261; P305 + P351 + P338
信号词:Warning
危险标志:GHS07
生产方法及用途
用途
有机合成中的氧化催化剂;金属表面处理。
有机合成中的氧化催化剂;金属表面处理。
合成路线
上游原料
下游产品
图谱
13C NMR : Predict

1H NMR : Predict

Mass spectrum (electron ionization)
