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化合物简介
n-Hexyllithium, C6H13Li, sometimes abbreviated to HxLi or NHL, is an organolithium compound used in organic synthesis as a strong base or as a lithiation reagent. It is usually encountered as a colorless or pale yellow solution in hexanes. Such solutions are highly sensitive to air and can ignite when treated with water.
基本信息
CAS:21369-64-2
中文别名:己基锂;
英文别名:lithium hexane;Lithium,hexyl;Hexyllithium solution;N-HEXYLLITHIUM;n-Hexyllithium;HxLi;Hexyllithium;
分子式:C6H13Li
分子量:92.1084
精确质量:92.1177
Psa:0.0
Logp:2.5343
中文别名:己基锂;
英文别名:lithium hexane;Lithium,hexyl;Hexyllithium solution;N-HEXYLLITHIUM;n-Hexyllithium;HxLi;Hexyllithium;
分子式:C6H13Li
分子量:92.1084
精确质量:92.1177
Psa:0.0
Logp:2.5343
编号系统
MDL号:MFCD00191446
PubChem号:24870524
EINECS号:404-950-0
BRN号:3600261
PubChem号:24870524
EINECS号:404-950-0
BRN号:3600261
物化性质
外观与性状:透明淡黄色至淡橙色溶液
密度:0.708 g/mL at 25ºC
沸点:68.5ºC at 760 mmHg
稳定性:Stable, but highly flammable. Reacts violently with water, releasing flammable gas. May spontaneously inflame in air. Moisture and air sensitive. Incompatible with water, alcohols, halocarbons.
储存条件:2-8ºC
密度:0.708 g/mL at 25ºC
沸点:68.5ºC at 760 mmHg
稳定性:Stable, but highly flammable. Reacts violently with water, releasing flammable gas. May spontaneously inflame in air. Moisture and air sensitive. Incompatible with water, alcohols, halocarbons.
储存条件:2-8ºC
安全信息
安全说明:S26-S30-S43-S45-S61-S62-S36-S37-S39
危险类别码:R11
危险品运输编码:UN 3394 4
海关编码:2931900090
危险类别:4.3
危险品标志:F; Xn; N; C
危险性防范说明:P210; P222; P223; P231 + P232; P370 + P378; P422
危险性描述:H225; H250; H260; H304; H314; H336; H361f; H373; H411
信号词:Danger
补充危害声明:与水剧烈反应。
危险标志:GHS02, GHS05, GHS07, GHS08, GHS09
危险类别码:R11
危险品运输编码:UN 3394 4
海关编码:2931900090
危险类别:4.3
危险品标志:F; Xn; N; C
危险性防范说明:P210; P222; P223; P231 + P232; P370 + P378; P422
危险性描述:H225; H250; H260; H304; H314; H336; H361f; H373; H411
信号词:Danger
补充危害声明:与水剧烈反应。
危险标志:GHS02, GHS05, GHS07, GHS08, GHS09
生产方法及用途
合成路线
上游原料
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图谱
13C NMR : Predict

1H NMR : Predict
