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化合物简介
Cobalt tetracarbonyl hydride is an organometallic compound with the formula HCo(CO)4. It is a volatile, yellow liquid that forms a colorless vapor and has an intolerable odor. The compound readily decomposes upon melt and in absentia of high CO partial pressures forms Co2(CO)8. Despite operational challenges associated with its handling, the compound has received considerable attention for its ability to function as a catalyst in hydroformylation. In this respect, HCo(CO)4 and related derivatives have received significant academic interest for their ability to mediate a variety of carbonylation reactions.
基本信息
CAS:16842-03-8
中文别名:
英文别名:cobalt hydridocarbonyl;tetracarbonylhydrido cobalt;(H)tetracarbonylcobalt;Cobalt hydrocarbonyl;cobalt tetracarbonyl hydride;Cobalt, tetracarbonylhydro-;COBALT,TETRACARBONYLHYDRO-;
分子式:C4HCoO4
分子量:171.982
精确质量:171.921
Psa:0.0
Logp:-0.3559
中文别名:
英文别名:cobalt hydridocarbonyl;tetracarbonylhydrido cobalt;(H)tetracarbonylcobalt;Cobalt hydrocarbonyl;cobalt tetracarbonyl hydride;Cobalt, tetracarbonylhydro-;COBALT,TETRACARBONYLHYDRO-;
分子式:C4HCoO4
分子量:171.982
精确质量:171.921
Psa:0.0
Logp:-0.3559
编号系统
UNII:33B757V1YU
物化性质
熔点:-26 °C
安全信息
生产方法及用途
合成路线
-
参考文献
Blanchard, A. A.; Gilmont, P. P.Gilmont, P.; Blanchard, A. A. Journal of the American Chemical SocietyJournal of the American Chemical Society, 1940, vol. 62Co: SVol.A, p. 1192 - 1193 doi: 10.1021/ja01862a057
上游原料
下游产品
图谱
Mass spectrum (electron ionization)
