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化合物简介
基本信息
CAS:13938-94-8
中文别名:二(三苯基膦)羰基氯化铑(I);氯化羰基双(三苯膦基)铑(I);羰基氯双(三苯基磷基)钌(I);双(三苯基膦)合氯化羰基铑(I);羰基双(三苯膦基)氯化铑(I);双(三苯基膦)羰基氯化铑(I);三苯基膦羰基氯化铑;
英文别名:Carbonylbis(triphenylphosphine)rhodium(I) Chloride;Bis(triphenylphosphine)carbonylrhodium(I) Chloride;methanone,rhodium(2+),triphenylphosphanium,chloride;Formylbis(triphenylphosphoranyl)rhodium(IV) chloride;Chlorocarbonylbis(triphenylphosphine)rhodium(I);Carbonylchlorobis(triphenylphosphine)rhodium(I);Rhodiumbis(triphenylphosphine) carbonyl chloride;
分子式:C37H32ClOP2Rh
分子量:692.955
精确质量:692.067
Psa:27.18
Logp:6.9266
中文别名:二(三苯基膦)羰基氯化铑(I);氯化羰基双(三苯膦基)铑(I);羰基氯双(三苯基磷基)钌(I);双(三苯基膦)合氯化羰基铑(I);羰基双(三苯膦基)氯化铑(I);双(三苯基膦)羰基氯化铑(I);三苯基膦羰基氯化铑;
英文别名:Carbonylbis(triphenylphosphine)rhodium(I) Chloride;Bis(triphenylphosphine)carbonylrhodium(I) Chloride;methanone,rhodium(2+),triphenylphosphanium,chloride;Formylbis(triphenylphosphoranyl)rhodium(IV) chloride;Chlorocarbonylbis(triphenylphosphine)rhodium(I);Carbonylchlorobis(triphenylphosphine)rhodium(I);Rhodiumbis(triphenylphosphine) carbonyl chloride;
分子式:C37H32ClOP2Rh
分子量:692.955
精确质量:692.067
Psa:27.18
Logp:6.9266
编号系统
EINECS号:237-712-8
BRN号:4618896
MDL号:MFCD00044273
PubChem号:24852243
BRN号:4618896
MDL号:MFCD00044273
PubChem号:24852243
物化性质
外观与性状:黄色晶体
熔点:224ºC
稳定性:Stable under normal temperatures and pressures.
储存条件:Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Do not expose to air. Store protected from moisture. Store under an inert atmosphere.
熔点:224ºC
稳定性:Stable under normal temperatures and pressures.
储存条件:Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Do not expose to air. Store protected from moisture. Store under an inert atmosphere.
安全信息
安全说明:S24/25
危险类别码:R20/21/22
海关编码:28439090
危险类别:6.1
包装等级:I; II; III
危险品标志:Xn
危险类别码:R20/21/22
海关编码:28439090
危险类别:6.1
包装等级:I; II; III
危险品标志:Xn
生产方法及用途
用途
催化剂。用于分子重排、烷基化、羧化、H交换、氧化还原反应。羰基化试剂。从酰氯合成酮类。
催化剂。用于分子重排、烷基化、羧化、H交换、氧化还原反应。羰基化试剂。从酰氯合成酮类。
合成路线
上游原料
下游产品
图谱
13C NMR : Predict

1H NMR : Predict

IR : KBr disc

IR : nujol mull
