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  • 乙烯基甲醚

    Methoxyethene

化合物简介

Methyl vinyl ether is an organic compound with the chemical formula C3H6O. It is the simplest chemical that contains both an alkene group and an alkyl group with an ether linkage. The compound can be made by reaction of acetylene and methanol in presence of a base. ; The alkene portion of the molecule is reactive in many ways. It is prone to polymerization, leading to formation of poly(methyl vinyl ether) (PMVE, CAS: 9003-09-2). This mode of reactivity is analogous to the way vinyl acetate and vinyl chloride can be polymerized to form polyvinyl acetate and polyvinyl chloride, respectively. The alkene can also react in [4+2] cycloaddition reactions. The reaction of it with acrolein is the first step in the commercial synthesis of glutaraldehyde.

基本信息

CAS:107-25-5
中文别名:甲基乙烯基醚;
英文别名:Methoxyethylene;methylvinyloxide;agrisynthmve;CH2=CHOCH3;methoxy-ethen;methyl vinyl ketone;ether,methylvinyl;methyleneoxyethylene;Metoxyethylene;vinyl methyl ether;1-methoxyethylene;Ethene,methoxy;methyl vinyl ether;mve;Ethene, methoxy-;
分子式:C3H6O
分子量:58.0791
精确质量:58.0419
Psa:9.23
Logp:0.7763

编号系统

EINECS号:203-475-4
MDL号:MFCD00008610
BRN号:1209255
RTECS号:KO2300000

物化性质

外观与性状:一种无色气体,带有香甜、愉快的气味
密度:0.73 g/ml
沸点:6°C
熔点:-122.2ºC
折射率:1.3730 (0ºC)
稳定性:Polymerizes easily.
储存条件:库房通风低温干燥,与氧化剂分开存放
蒸汽压:1500mmHg at 25°C

安全信息

安全说明:S9-S16-S33
危险类别码:R12
危险品运输编码:UN 1087
海关编码:2909199090
危险类别:2.1
危险品标志:F+

生产方法及用途

生产方法
由甲醇与乙炔在氢氧化钾催化下先制备出乙醛缩二甲醇【CH3CH(OC 用于生产戊二醛及高分子材料、涂料、增塑剂、粘合剂等。
用途
用于生产戊二醛及高分子材料、涂料、增塑剂、粘合剂等。

合成路线

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图谱

Predict 1H proton NMR


13C NMR : Predict


1H NMR : Predict


Mass spectrum (electron ionization)


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