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1-羟基四苯基环戊二烯基(四苯基-2,4-环戊二烯基-1-酮)-μ-羟基四羰基二钌(II)
1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-?hydrotetracarbonyldiruthenium(II), 98% SHVO'S CATALYST
化合物简介
The Shvo catalyst, named after Youval Shvo, is an organoruthenium compound that is used for transfer hydrogenation. Related derivatives are known where p-tolyl replaces some of the phenyl groups. The compound is of academic interest as an early example of a catalyst for transfer hydrogenation that operates by an \"outer sphere mechanism.\" ; Commonly, industrial hydrogenation processes involve heterogeneous catalysts containing one or more transition metals. While this approach facilitates efficient production on an industrial scale, heterogeneous catalysis is not always suitable for the asymmetric synthesis of more structurally complex molecules, which demands the increased versatility precluded by necessary interaction with a solid metal surface.
基本信息
CAS:104439-77-2
中文别名:1-羟基四苯基环戊二烯基(四苯基-2,4-环戊二烯-1-酮)-μ-氢四羰基二钌(II);
英文别名:SHVO\'S CATALYST;
分子式:C62H41O6Ru2
分子量:1084.13
精确质量:1085.1
Psa:37.3
Logp:10.9762
中文别名:1-羟基四苯基环戊二烯基(四苯基-2,4-环戊二烯-1-酮)-μ-氢四羰基二钌(II);
英文别名:SHVO\'S CATALYST;
分子式:C62H41O6Ru2
分子量:1084.13
精确质量:1085.1
Psa:37.3
Logp:10.9762
编号系统
PubChem号:24884974
物化性质
熔点:223-227ºC
安全信息
安全说明:S22-S24/25
生产方法及用途
合成路线
上游原料
下游产品
图谱
1H NMR : Predict

13C NMR : Predict
